Room-temperature ferromagnetism in Sr1-xYxCoO3-δ (0.2 ≤ x ≤ 0.25) -: art. no. 104408

被引:84
作者
Kobayashi, W [1 ]
Ishiwata, S
Terasaki, I
Takano, M
Grigoraviciute, I
Yamauchi, H
Karppinen, M
机构
[1] Waseda Univ, Dept Appl Phys, Tokyo 1698555, Japan
[2] Japan Sci & Technol Agcy, CREST, Tokyo 1080075, Japan
[3] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan
关键词
D O I
10.1103/PhysRevB.72.104408
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have measured magnetic susceptibility and resistivity of Sr1-xYxCoO3-delta (x=0.1, 0.15, 0.2, 0.215, 0.225, 0.25, 0.3, and 0.4), and found that Sr1-xYxCoO3-delta is a room temperature ferromagnet with a Curie temperature of 335 K in a narrow compositional range of 0.2 <= x <= 0.25. This is the highest transition temperature among perovskite Co oxides. The saturation magnetization for x=0.225 is 0.25 mu(B)/Co at 10 K, which implies that the observed ferromagnetism is a bulk effect. We attribute this ferromagnetism to a peculiar Sr/Y ordering.
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共 25 条
[1]   La0.95Sr0.05CoO3:: An efficient room-temperature thermoelectric oxide [J].
Androulakis, J ;
Migiakis, P ;
Giapintzakis, J .
APPLIED PHYSICS LETTERS, 2004, 84 (07) :1099-1101
[2]   MUON-SPIN-RELAXATION STUDY OF MAGNETIC ORDER IN RNIO(3) (R EQUALS RARE-EARTH) BELOW THE METAL-INSULATOR-TRANSITION [J].
GARCIAMUNOZ, JL ;
LACORRE, P ;
CYWINSKI, R .
PHYSICAL REVIEW B, 1995, 51 (21) :15197-15202
[3]   Structural and magnetic properties of Y0.33Sr0.67CoO2.79 -: art. no. 134411 [J].
Goossens, DJ ;
Wilson, KF ;
James, M ;
Studer, AJ ;
Wang, XL .
PHYSICAL REVIEW B, 2004, 69 (13) :134411-1
[4]   Synthesis and characterization of Sr1-xLnxCoO3-δ, Ln = Y, Srn-Tm, 0.1≤x≤0.5 [J].
Istomin, SY ;
Drozhzhin, OA ;
Svensson, G ;
Antipov, EV .
SOLID STATE SCIENCES, 2004, 6 (06) :539-546
[5]   Crystal structure of the novel complex cobalt oxide Sr0.7Y0.3CoO2.62 [J].
Istomin, SY ;
Grins, J ;
Svensson, G ;
Drozhzhin, OA ;
Kozhevnikov, VL ;
Antipov, EV ;
Attfield, JP .
CHEMISTRY OF MATERIALS, 2003, 15 (21) :4012-4020
[6]   The phase diagram and tetragonal superstructures of the rare earth cobaltate phases Ln1-xSrxCoO3-δ (Ln = La3+, Pr3+, Nd3+, Sm3+, Gd3+, Y3+, Ho3+, Dy3+, Er3+, Tm3+ and Yb3+) [J].
James, M ;
Cassidy, D ;
Goossens, DJ ;
Withers, RL .
JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (06) :1886-1895
[7]   Oxygen content analysis of functional perovskite-derived cobalt oxides [J].
Karppinen, M ;
Matvejeff, M ;
Salomäki, K ;
Yamauchi, H .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (06) :1761-1764
[8]   ORBITAL AND MAGNETIC STRUCTURE OF 2-DIMENSIONAL FERROMAGNETS WITH JAHN-TELLER IONS [J].
KHOMSKII, DI ;
KUGEL, KI .
SOLID STATE COMMUNICATIONS, 1973, 13 (07) :763-766
[9]  
KOBAYASHI W, 2005, P INT C PER PROP POT
[10]   Effect of iron doping on the properties of TbBaCo2O5.5 layered perovskite [J].
Kopcewicz, M ;
Khalyavin, DD ;
Troyanchuk, IO ;
Szymczak, H ;
Szymczak, R ;
Logvinovich, DJ ;
Naumovich, EN .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (01) :479-486