A FT-IR study of the reactivity of tungsta-supported catalysts toward butan-2-ol

被引：11

作者：

Carrazán, SRG ^{[1
]}

Martín, C ^{[1
]}

Solana, G ^{[1
]}

Rives, V ^{[1
]}

机构：

[1] Univ Salamanca, Dept Quim Inorgan, E-37008 Salamanca, Spain

来源：

LANGMUIR | 2001年 / 17卷 / 22期

关键词：

D O I：

10.1021/la010428r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The surface acid properties of WOx supported on different oxides (alumina, silica, magnesia, titania, zirconia, and niobia), as well as the decomposition of butan-2-ol on these systems, have been studied by FT-IR spectroscopy. Incorporation of supported tungsten-containing species significantly increases the surface acid properties, and new surface acid sites develop, except for in the magnesia-supported system. The increase in surface acidity is responsible for the high selectivity to butene formation on these systems, except for in the magnesia-supported system, where a larger selectivity to methyl ethyl ketone is observed.

引用

页码：6968 / 6973

页数：6

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