Synthesis and structure of a novel MoFe4S4 cubane-like cluster (Me3 PhCH2N)2[MoFe4S4(SC6H11)7]

被引：1

作者：

Chen, CN

Deng, YH

Hong, MC

Wen, TB

Zhang, CX

Liu, QT ^{[1
]}

Lu, JX

Chen, XM

Kang, BS

Zhou, ZY

Mak, TCW

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

[2] Zhongshan Univ, Dept Chem, Guangzhou 510275, Peoples R China

[3] Chinese Univ Hong Kong, Dept Chem, Shatin, Peoples R China

来源：

SCIENCE IN CHINA SERIES B-CHEMISTRY | 1998年 / 41卷 / 03期

基金：

中国国家自然科学基金;

关键词：

molybdenum iron sulfur cluster; single cubane cluster; crystal structure; iron cluster;

D O I：

10.1007/BF02879711

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel (Me3PhCH2N)(2)[MoFe4S4(SC6H11)(7)] cubane-like cluster was obtained from a reaction system including (NH4)(2)MoS4, FeCl2 and NaSC6H11 in methanol, and characterized by X-ray crystallography. The title compound crystallizes in triclinic space group <P(1)over bar> with a = 1.523 1(3), b = 1.610 5(3), c = 1.838 3(4) nm, alpha = 77.18 (3)degrees, beta = 75.17(3)degrees, gamma = 64.60 (3)degrees, and Z = 2. Also included in this paper are the discussions on the variation of the reaction products obtained from the participation of cyclohexylthiolate and on the changes of the structural features of the products.

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收藏

页码：301 / 308

页数：8

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