Palladium-catalyzed hydroselenation of allenes with benzeneselenol

被引：31

作者：

Ogawa, A ^{[1
]}

Kudo, A ^{[1
]}

Hirao, T ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 565, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 29期

关键词：

D O I：

10.1016/S0040-4039(98)01024-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium(II) acetate (Pd(OAc)(2)) catalyzes the addition of benzeneselenol to allenes, providing the corresponding vinylic selenides in good yields. In contrast to the oxygen-induced radical addition of PhSe11 to terminal allenes, which occurred at the terminal double bond preferentially, the present palladium-catalyzed hydroselenation to terminal allenes affords the internal adduct preferentially; thus, these two reactions are complementary to each other for the synthesis of vinylic selenides. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：5213 / 5216

页数：4

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