First total synthesis of (±)-taxifolial A and (±)-iso-caulerpenyne

被引：26

作者：

Commeiras, L ^{[1
]}

Santelli, M ^{[1
]}

Parrain, JL ^{[1
]}

机构：

[1] Fac Sci & Tech St Jerome, CNRS UMR 6009, Lab Synth Organ Associe, F-13397 Marseille 20, France

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 11期

关键词：

D O I：

10.1021/ol015903r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first synthesis of (+/-) taxifolial A and iso-caulerpenyne was accomplished. The key steps in the sequence are (1) the stereoselective assembly of a vinyltin derived from butynediol and a functionalized aldehyde and (2) the construction of the dienyne moiety via a Stille cross-coupling.

引用

页码：1713 / 1715

页数：3

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