Ring-opening polymerization of gold macrocycles and self-assembly of a coordination polymer through hydrogen-bonding

被引:93
作者
Burchell, TJ [1 ]
Eisler, DJ [1 ]
Jennings, MC [1 ]
Puddephatt, RJ [1 ]
机构
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
关键词
D O I
10.1039/b306004g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The equilibrium between digold and tetragold rings and a ring-opened oligomer and polymer is established by NMR and ESI-MS studies in solution and by structure determinations in the solid state; the polymer containing amide-derivatized ligands undergoes self-assembly through hydrogen bonding to give an ordered network.
引用
收藏
页码:2228 / 2229
页数:2
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