Three-dimensional photoluminescent pillared metal-organic framework with 4.82 topological channels obtained from the assembly of cadmium(II) acetate and trimellitic salt

被引：60

作者：

Fan, J

Zhu, HF

Okamura, TA

Sun, WY ^{[1
]}

Tang, WX

Ueyama, N

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Osaka 5600043, Japan

来源：

NEW JOURNAL OF CHEMISTRY | 2003年 / 27卷 / 10期

关键词：

D O I：

10.1039/b304826h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the piperidinium salt of trimellitic acid (BTC3-) with cadmium(II) acetate dihydrate yields an unprecedented 3D pillared metal-organic framework, [Cd-3(BTC)(2)(H2O)(6)].3H(2)O, showing strong blue luminescence. The framework contains 4.8(2) topological channels, in which the 'floors' are directly connected by the pillars of the BTC3- benzene rings.

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收藏

页码：1409 / 1411

页数：3

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