The absolute configuration of heptahelicene:: a VCD spectroscopy study

被引：63

作者：

Bürgi, T

Urakawa, A

Behzadi, B

Ernst, KH

Baiker, A

机构：

[1] ETH Honggerberg, Inst Chem & Bioengn, CH-8093 Zurich, Switzerland

[2] Swiss Fed Labs Mat Testing & Res, CH-8600 Dubendorf, Switzerland

来源：

NEW JOURNAL OF CHEMISTRY | 2004年 / 28卷 / 03期

关键词：

D O I：

10.1039/b312877f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The comparison between experimental and calculated VCD spectra allowed the unequivocal assignment of the absolute configuration of heptahelicene C30H18 as P(+).

引用

页码：332 / 334

页数：3

共 28 条

[1] Ashitaka H., 1995, Nonlinear Optics, Principles, Materials, Phenomena, and Devices, V14, P81
[2] Chiroptical properties from time-dependent density functional theory. II. Optical rotations of small to medium sized organic molecules
Autschbach, J
Patchkovskii, S
Ziegler, T
van Gisbergen, SJA
Baerends, EJ
[J]. JOURNAL OF CHEMICAL PHYSICS, 2002, 117 (02) : 581 - 592
[3] THEORETICAL OPTICAL-ROTATION OF ORIENTED HEXAHELICENE
BARRON, LD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1975, 71 (02): : 293 - 300
[4] Electro-optic response of chiral helicenes in isotropic media
Beljonne, D
Shuai, Z
Brédas, JL
Kauranen, M
Verbiest, T
Persoons, A
[J]. JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (04) : 1301 - 1304
[5] Beurskens P. T., 1976, CRYST STRUCT COMMUN, V5, P247
[6] Beurskens P. T., 1976, CRYST STRUCT COMMUN, V5, P241
[7] DETERMINATION OF THE ABSOLUTE CONFIGURATION OF OPTICALLY ACTIVE COMPOUNDS BY MEANS OF X-RAYS
BIJVOET, JM
PEERDEMAN, AF
VANBOMMEL, AJ
[J]. NATURE, 1951, 168 (4268) : 271 - 272
[8] PI-ELECTRON ABSORPTION AND CIRCULAR DICHROISM SPECTRA OF [6]-HELICENE AND [7]-HELICENE
BRICKELL, WS
BROWN, A
KEMP, CM
MASON, SF
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (05): : 756 - &
[9] VCD spectroscopy of chiral cinchona modifiers used in heterogeneous enantioselective hydrogenation:: conformation and binding of non-chiral acids
Bürgi, T
Vargas, A
Baiker, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2002, (09): : 1596 - 1601
[10] Electronic structure calculations on helicenes. Concerning the chirality of helically twisted aromatic systems
Buss, V
Kolster, K
[J]. CHEMICAL PHYSICS, 1996, 203 (03) : 309 - 316

← 1 2 3 →