The synthesis and solid-state and solution structures of an unprecedented mixed chiral α-amino lithium alkoxide lithium alkoxide aggregate

被引：14

作者：

Clegg, W

Liddle, ST

Snaith, R

Wheatley, AEH

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

NEW JOURNAL OF CHEMISTRY | 1998年 / 22卷 / 12期

关键词：

D O I：

10.1039/a807593j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lithium N,N,N'-trimethylethylenediamide, LiN(Me)(CH2)(2)NMe2, reacts with 1 equiv. of 2-trifluoromethylbenzaldehyde, 2-F3CC6H4CHO, to afford a surprising tetranuclear mixed aggregate containing three chiral or-amino lithium alkoxide molecules which associate in a highly unusual fashion, the fourth molecule, the benzyl alkoxide reduction product, forming by an inter-molecular LiH transfer.

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页码：1323 / 1326

页数：4

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