Anomalous reactivity of diphenylhydroxymethylphosphine oxide in the synthesis of a phosphorylated ether by oxa-Michael reaction

被引：21

作者：

Cristau, HJ ^{[1
]}

Virieux, D ^{[1
]}

机构：

[1] ENSCM, CNRS, Chim Organ Lab, F-34296 Montpellier 5, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(98)02482-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Vinylic phosphorus compounds were found to react as Michael olefins with alcohols in basic catalytic conditions. Several phosphorylated polyethers were obtained in such a way. In analogous conditions, the hydroxymethylphosphine oxide used as alcoholic reagent looses formaldehyde leading to 1,2-diphosphorus compound formation. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：703 / 706

页数：4

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