Direct metalation of a phthalocyanine monolayer on Ag(111) with coadsorbed iron atoms

被引：124

作者：

Bai, Yun

Buchner, Florian

Wendahl, Matthew T.

Kellner, Ina

Bayer, Andreas

Steinrueck, Hans-Peter

Marbach, Hubertus

Gottfried, J. Michael

机构：

[1] Univ Erlangen Nurnberg, Lehrstuhl Phys Chem 2, D-91058 Erlangen, Germany

[2] Interdisciplinary Ctr Mol Mat, D-91058 Erlangen, Germany

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2008年 / 112卷 / 15期

关键词：

D O I：

10.1021/jp711122w

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An ordered monolayer of phthalocyanine on a silver(111) surface reacts with the stoichiometric amount of coadsorbed Fe atoms to form iron(II)-phthalocyanine. This surface-confined redox reaction was studied with X-ray photoelectron spectroscopy (XPS) and scanning tunneling microscopy (STM). The formation of iron(II)-phthalocyanine was confirmed by comparison with the directly deposited complex. No side reactions such as the coordination of Fe atoms on the peripheral nitrogen atoms of the phthalocyanine molecules were observed.

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页码：6087 / 6092

页数：6

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