Biosynthesis of striatol in cultured cells of liverwort, Ptycanthus striatus

被引：9

作者：

Katoh, K

Yamamoto, K

Yamamoto, M

Hashimoto, M

Nabeta, K ^{[1
]}

机构：

[1] Obihiro Univ Agr & Vet Med, Dept Bioresource Sci, Obihiro, Hokkaido 0808555, Japan

[2] Shionogi & Co Ltd, Shionogi Res Labs, Aburahi Labs, Shiga 5203423, Japan

来源：

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 1998年 / 62卷 / 12期

关键词：

liverwort; Ptycanthus striatus; striatol biosynthesis; cyclization; 1,2-migration;

D O I：

10.1271/bbb.62.2480

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

NMR analyses of striatol produced by suspension-cultured cells of liverwort, Ptycanthus striatus, in the presence of [2-C-13]- and [4,4-H-2(2)]-MVAs confirmed proton-catalyzed cyclization between the distal and central double bonds in FPP and a concerted series of 1,2-migrations of hydrogen and a methyl group, with subsequent elimination of a proton.

引用

页码：2480 / 2482

页数：3

共 10 条

[1]

Asakawa Y., 1995, Progress in the Chemistry of Organic Natural Products, V65, P1, DOI 10.1007/978-3-7091-6896-7_1

[2] BIOSYNTHESIS OF FERN-9-ENE IN POLYPODIUM VULGARE LINN [J].