Stabilized blue emission from polyfluorene-based light-emitting diodes: The role of triphenylamine

被引:40
作者
Giovanella, Umberto [1 ]
Pasini, Mariacecilia [1 ]
Destri, Silvia [1 ]
Porzio, William [1 ]
Botta, Chiara [1 ]
机构
[1] CNR, Ist Chim Macromol, I-20133 Milan, Italy
关键词
polyfluorene; electroluminescence; fluorenone; triphenylamine; antioxidant; green emission;
D O I
10.1016/j.synthmet.2007.12.007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A deep study of the optical properties related to the performances in light-emitting diodes (LEDs) of a fluorene-based copolymer containing triphenylamine (TPA), showed a huge reduction of oxidation of the whole material, a macromolecule separation, hence preventing the crystalline aggregation, an improved time-stability of both material chromaticity and morphology compared with commercial poly(9,9-dioctylfluorene) (PFO). LED device prototypes based on this copolymer exploited enhanced performances with respect to commercial PFO prepared under the same conditions. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:113 / 119
页数:7
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