Shaping supramolecular nanoribers with nanoparticles forming complementary hydrogen bonds

被引:76
作者
Puigmarti-Luis, Josep [1 ,2 ]
Del Pino, Angel Pez [1 ]
Laukhina, Elena [1 ]
Esquena, Jordi [3 ]
Laukhin, Vladimir [4 ]
Rovira, Concepci [1 ]
Vidal-Gancedo, Jose [1 ]
Kanaras, Antonios G. [5 ]
Nichols, Richard J. [5 ]
Brust, Mathias [5 ]
Amabilino, David B. [1 ]
机构
[1] CSIC, Dept Nanosci Mol & Mat Organ, Inst Ciencia Mat Barcelona, Bellaterra 08193, Spain
[2] ICN, Bellaterra 08193, Spain
[3] CSIC, IIQAB, Barcelona, Spain
[4] ICREA, Barcelona, Spain
[5] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
关键词
conducting materials; gels; hydrogen bonds; nanostructures; supramolecular chemistry;
D O I
10.1002/anie.200704864
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Functionalized gold nanoparticles with complementary H-bonding groups can control the secondary structure of xerogel fibers formed by a molecular conductor thanks to their incorporation into the nanowires, which show metal-like conductivity once doped without the need for annealing. The picture shows a photograph of the xerogel, TEM images of Au particles in the gel and a single fiber, and an AFM image revealing the texture of the gel. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1861 / 1865
页数:5
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