Membranes of Vertically Aligned Superlong Carbon Nanotubes

被引:115
作者
Du, Feng [1 ,2 ,3 ]
Qu, Liangti [3 ,4 ]
Xia, Zhenhai [5 ]
Feng, Lianfang [6 ]
Dai, Liming [1 ,2 ,3 ]
机构
[1] Case Western Reserve Univ, Case Sch Engn, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA
[2] Case Western Reserve Univ, Case Sch Engn, Dept Chem Engn, Cleveland, OH 44106 USA
[3] Univ Dayton, Sch Engn, Dept Chem & Mat Engn, Dayton, OH 45469 USA
[4] Beijing Inst Technol, Sch Sci, Dept Chem, Key Lab Cluster Sci, Beijing 100081, Peoples R China
[5] Univ N Texas, Dept Mat Sci & Engn, Denton, TX 76203 USA
[6] Zhejiang Univ, Dept Chem & Biol Engn, State Key Lab Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China
基金
美国国家科学基金会;
关键词
COMPOSITES; TRANSPORT; SIDEWALL; FRACTION; CHANNEL; ARRAYS; FLOW;
D O I
10.1021/la200995r
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the present work, we have developed a simple but effective method to prepare superlong vertically aligned carbon nanotubes (SLVA-CNT) and epoxy composite membranes, and we have demonstrated that various liquids, including water, hexane, and dodecane, can effectively pass through the SLVA-CNT membranes. These results were confirmed by molecular dynamics simulations, While the mechanical densification was used to further enhance the flow transport through the SLVA-CNT membranes, we developed in this study a magnetic-nanoparticle switching system to turn on and off the flow through the nanotube membrane by simply applying an alternating voltage. The methodologies developed in this study should have a significant implication to the development of various smart membranes for advanced intelligent systems.
引用
收藏
页码:8437 / 8443
页数:7
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