New Li-ion electrolytes for low temperature applications

被引:108
作者
Herreyre, S
Huchet, O
Barusseau, S
Perton, F
Bodet, JM
Biensan, P
机构
[1] SAFT, DRE, F-33074 Bordeaux, France
[2] SAFT, F-86060 Poitiers, France
关键词
Li-ion cell; liquid electrolyte; low temperature; ester;
D O I
10.1016/S0378-7753(01)00670-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ethyl acetate and methyl butyrate have been tested as new solvents for Li-ion liquid electrolytes. Specific ternary mixtures have been investigated, containing cyclic carbonate and linear carbonate solvents in addition to the esters. Thanks to their high conductivities, these electrolytes make it possible to obtain very good performances below -30 degreesC, in different LiCoO2//graphite cells. Moreover, these electrolyte compositions do not affect cyclability, charge retention of safety of the LiCoO2 cells, behaving as pure carbonate electrolytes. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:576 / 580
页数:5
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