Isothermal crystallization of nylon 6/liquid crystal copolyester blends

被引:14
作者
Campoy, I [1 ]
Gómez, MA [1 ]
Marco, C [1 ]
机构
[1] CSIC, Inst Ciencia & Tecnol Polimeros, E-28006 Madrid, Spain
关键词
nylon; 6; liquid crystal copolyester; blends;
D O I
10.1016/S0032-3861(98)00652-1
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The isothermal crystallization behaviour has been investigated for several compositions of blends between nylon 6 (N6) and the liquid crystal copolyester Vectra using calorimetric and X-ray diffraction techniques. Differences in the crystallization rates have been related to the structural properties of these systems by means of WAXS and SAXS real time experiments using synchrotron radiation. Other kinetic parameters such as the Avrami exponents, the equilibrium melting temperatures, and the interfacial free energies have been determined from the calorimetric data. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:4259 / 4271
页数:13
相关论文
共 38 条
[1]  
[Anonymous], 1960, KUNSTSTOFFEN EIGENSC
[2]   Granulation, Phase Change, and Microstructure - Kinetics of Phase Change. III [J].
Avrami, M .
JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (02) :177-184
[3]   Kinetics of phase change I - General theory [J].
Avrami, M .
JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (12) :1103-1112
[4]  
Avrami M., 1940, J CHEM PHYS, V8, P212, DOI [10.1063/1.1750631, DOI 10.1063/1.1750631]
[5]  
BARK M, 1992, MAKROMOL CHEM, V193, P2363
[6]   CRYSTALLIZATION OF POLYMER MELTS UNDER FAST COOLING .1. NUCLEATED POLYAMIDE-6 [J].
BRUCATO, V ;
CRIPPA, G ;
PICCAROLO, S ;
TITOMANLIO, G .
POLYMER ENGINEERING AND SCIENCE, 1991, 31 (19) :1411-1416
[7]   CRYSTALLIZATION KINETICS IN RELATION TO POLYMER PROCESSING [J].
BRUCATO, V ;
PICCAROLO, S ;
TITOMANLIO, G .
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1993, 68 :245-255
[8]  
BURNETT B, 1957, J APPL PHYS, V28, P1001
[9]   CRYSTALLIZATION KINETICS OF POLYPROPYLENE-POLYAMIDE COMPATIBILIZED BLENDS [J].
CAMPOY, I ;
ARRIBAS, JM ;
ZAPORTA, MAM ;
MARCO, C ;
GOMEZ, MA ;
FATOU, JG .
EUROPEAN POLYMER JOURNAL, 1995, 31 (05) :475-480
[10]   Thermogravimetric analysis of blends based on Nylon 6 and a thermotropic liquid crystal copolyester [J].
Campoy, I ;
Gomez, MA ;
Marco, C .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 1998, 52 (03) :705-715