Simulation in electrochemistry using the finite element method part 2: scanning electrochemical microscopy

被引:33
作者
Nann, T [1 ]
Heinze, Y [1 ]
机构
[1] Univ Freiburg, Inst Phys Chem, D-79104 Freiburg, Germany
关键词
simulation; SECM; adaptive finite element method;
D O I
10.1016/S0013-4686(03)00312-8
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The previously introduced adaptive finite element (AFE) algorithm for use in electrochemistry is applied to the simulation of selected multidimensional problems: steady state simulation, chronoamperometric simulation, cyclic voltammetry at microelectrodes, and simulation of arbitrarily shaped scanning electrochemical microscope (SECM) tips. It is shown that the algorithm is suitable for this kind of problems and can be easily extended to the simulation of many types of electrochemical experiments. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3975 / 3980
页数:6
相关论文
共 36 条
[1]   Laser-activated voltammetry.: Mechanism of aqueous iodide oxidation at platinum electrodes:: Theory and experiment [J].
Akkermans, RP ;
Qiu, FL ;
Roberts, SL ;
Suárez, MF ;
Compton, RG .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (39) :8319-8327
[2]   Equivalence between microelectrodes of different shapes: Between myth and reality [J].
Amatore, C ;
Fosset, B .
ANALYTICAL CHEMISTRY, 1996, 68 (24) :4377-4388
[3]   SCANNING ELECTROCHEMICAL MICROSCOPY - THEORY AND APPLICATION OF THE TRANSIENT (CHRONOAMPEROMETRIC) SECM RESPONSE [J].
BARD, AJ ;
DENAULT, G ;
FRIESNER, RA ;
DORNBLASER, BC ;
TUCKERMAN, LS .
ANALYTICAL CHEMISTRY, 1991, 63 (13) :1282-1288
[4]   SCANNING ELECTROCHEMICAL MICROSCOPY - INTRODUCTION AND PRINCIPLES [J].
BARD, AJ ;
FAN, FRF ;
KWAK, J ;
LEV, O .
ANALYTICAL CHEMISTRY, 1989, 61 (02) :132-138
[5]  
BARD AJ, 1980, ELECTROCHEMICAL METH
[6]  
BORGWARTH K, 1996, OBERFLACHENANALYSE S
[7]  
Britz D., 1988, DIGITAL SIMULATION E
[8]   MODELING THE DEGRADATION OF SCANNING ELECTROCHEMICAL MICROSCOPE IMAGES DUE TO SURFACE-ROUGHNESS [J].
ELLIS, KA ;
PRITZKER, MD ;
FAHIDY, TZ .
ANALYTICAL CHEMISTRY, 1995, 67 (24) :4500-4507
[9]   MEASUREMENTS WITHIN THE DIFFUSION LAYER USING A MICROELECTRODE PROBE [J].
ENGSTROM, RC ;
WEBER, M ;
WUNDER, DJ ;
BURGESS, R ;
WINQUIST, S .
ANALYTICAL CHEMISTRY, 1986, 58 (04) :844-848
[10]   Finite element simulation of the chronoamperometric response of recessed and protruding microdisc electrodes [J].
Ferrigno, R ;
Brevet, PF ;
Girault, HH .
ELECTROCHIMICA ACTA, 1997, 42 (12) :1895-1903