Recent advances in catalytic hydrogenation of carbon dioxide

被引:2807
作者
Wang, Wei [1 ]
Wang, Shengping [1 ]
Ma, Xinbin [1 ]
Gong, Jinlong [1 ]
机构
[1] Tianjin Univ, Sch Chem Engn & Technol, Minist Educ, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China
基金
中国国家自然科学基金;
关键词
GAS-SHIFT REACTION; FISCHER-TROPSCH SYNTHESIS; DIMETHYL ETHER SYNTHESIS; RICE HUSK ASH; COPPER-ZIRCONIA CATALYSTS; GROUP-VIII METALS; RUTHENIUM TRIMETHYLPHOSPHINE COMPLEXES; METHANOL-SYNTHESIS CATALYST; ACID-BASE-EQUILIBRIUM; LIQUID-PHASE METHANOL;
D O I
10.1039/c1cs15008a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Owing to the increasing emissions of carbon dioxide (CO2), human life and the ecological environment have been affected by global warming and climate changes. To mitigate the concentration of CO2 in the atmosphere various strategies have been implemented such as separation, storage, and utilization of CO2. Although it has been explored for many years, hydrogenation reaction, an important representative among chemical conversions of CO2, offers challenging opportunities for sustainable development in energy and the environment. Indeed, the hydrogenation of CO2 not only reduces the increasing CO2 buildup but also produces fuels and chemicals. In this critical review we discuss recent developments in this area, with emphases on catalytic reactivity, reactor innovation, and reaction mechanism. We also provide an overview regarding the challenges and opportunities for future research in the field (319 references).
引用
收藏
页码:3703 / 3727
页数:25
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