Synthesis and characterization of a new benzofulvene polymer showing a thermoreversible polymerization behavior

被引:70
作者
Cappelli, A
Mohr, GL
Anzini, M
Vomero, S
Donati, A
Casolaro, M
Mendichi, R
Giorgi, G
Makovec, F
机构
[1] Univ Siena, Dipartimento Farmacochim Tecnol, I-53100 Siena, Italy
[2] Univ Siena, Dipartimento Sci Chim & Biosistemi, I-53100 Siena, Italy
[3] CNR, Ist Studio Macromol, I-20133 Milan, Italy
[4] Univ Siena, Ctr Interdipartimento Anal & Determinaz Struttura, I-53100 Siena, Italy
[5] Rotta Res Lab SpA, I-20052 Monza, Italy
关键词
D O I
10.1021/jo035104h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new polymer based on a functionalized benzofulvene moiety has been synthesized by spontaneous polymerization of the monomer in the solid state. This polymer shows a very high molar mass, high solubility in the most common organic solvents, and thermoreversible polymerization properties. An interesting application in synthesis is reported.
引用
收藏
页码:9473 / 9476
页数:4
相关论文
共 11 条