Surface modification of graphite anodes by combination of high temperature gas treatment and silylation in nonaqueous solution

被引：35

作者：

Buqa, H

Grogger, C

Alvarez, MVS

Besenhard, JO

Winter, M

机构：

[1] Graz Univ Technol, Inst Chem Technol Inorgan Mat, A-8010 Graz, Austria

[2] Graz Univ, Inst Inorgan Chem, A-8010 Graz, Austria

来源：

JOURNAL OF POWER SOURCES | 2001年 / 97-8卷

关键词：

lithium-ion battery; graphite anode; surface modification; silane coupling; solid electrolyte interphase;

D O I：

10.1016/S0378-7753(01)00524-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Graphite surface modification by silylation in nonaqueous solution has been examined. Silane coupling with hydroxyl-containing carbon surface species, such as hydroxyl-groups and adsorbed water is assumed to be the main surface reaction introduced by this modification treatment. In terms of reduced irreversible charge losses, best results were obtained when graphites pre-oxidized in oxygen atmosphere at elevated temperatures have been silylated. (C) 2001 EIsevier Science B.V. All rights reserved.

引用

页码：126 / 128

页数：3

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