One-pot four-component reaction:: Aqueous TiCl3/PhN2+-mediated alkyl radical addition to imines generated in situ

被引：37

作者：

Cannella, R ^{[1
]}

Clerici, A ^{[1
]}

Pastori, N ^{[1
]}

Regolini, E ^{[1
]}

Porta, O ^{[1
]}

机构：

[1] Politecn Milan, Sez Chim, Dipartimento Chim Mat & Ingn Chim Giulio Natta, I-20131 Milan, Italy

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 04期

关键词：

D O I：

10.1021/ol047595d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ti(III)-induced free-radical decomposition of a phenyldiazonium salt, followed by phenyl radical iodine-atom abstraction from alkyl iodides, leads to a one-pot selective alkyl radical addition to the C-atom of imines generated in situ under aqueous acidic conditions.

引用

页码：645 / 648

页数：4

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