Electrochemical synthesis and structural characterization of the trinuclear copper(I)-copper(II) complex: bis[bis(triphenylphosphine)copper(I)] [bis(thiosalicylate)copper(II)]

被引：18

作者：

Bott, RC

Healy, PC ^{[1
]}

Sagatys, DS

机构：

[1] Griffith Univ, Sch Sci, Brisbane, Qld 4111, Australia

[2] Queensland Univ Technol, Sch Phys Sci, Brisbane, Qld 4000, Australia

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 21期

关键词：

D O I：

10.1039/a806813e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel, symmetrical trinuclear copper(I)-copper(II) complex, bis[bis(triphenylphosphine)copper(I)] [bis(thiosalicylate)copper(II)], [{Cu(PPh3)(2)}(2){Cu(C7H4O2S)(2)}], has been prepared by anodic dissolution of copper into a solution of triphenylphosphine and thiosalicylic acid in acetonitrile and characterized by single crystal X-ray structure determination as its acetonitrile solvate; characterized also is the 1:3 copper(I) complex, [tris(triphenylphosphine)(thiosalicylic acid-S)copper(I)], formed as an intermediate in the electrosynthesis.

引用

页码：2403 / 2404

页数：2

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