Nanofibers of 1,3-diphenyl-2-pyrazoline induced by cetyltrimethylammonium bromide micelles

被引：127

作者：

Fu, HB ^{[1
]}

Xiao, DB ^{[1
]}

Yao, JN ^{[1
]}

Yang, GQ ^{[1
]}

机构：

[1] Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 25期

关键词：

aggregation; micelles; nanostructures; photochemistry; pi interactions;

D O I：

10.1002/anie.200350961

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A self-inducing template-growth approach to the production of nanofibers of 1,3-diphenyl-2-pyrazoline (DP) in the presence of cetyltrimethylammonium bromide (CTAB) in an aqueous phase is discussed (see picture). Not only the surfactant CTAB molecules assume the role of surface-active colloidal stabilizers; but also the rodlike CTAB micelles, which are induced by DP molecules dissolved in spherical CTAB micelles, further direct the growth of cylindrical DP nanofibers like templates. It is found that the crystal-packing forces drive the DP molecules to self-assemble as J-type aggregates in nanofibers.

引用

页码：2883 / 2886

页数：4

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