Self-inclusion and paraffin intercalation of the p-tert-butylcalix[4]arene host:: a neutral organic clay mimic

被引：84

作者：

Brouwer, EB ^{[1
]}

Udachin, KA ^{[1
]}

Enright, GD ^{[1
]}

Ripmeester, JA ^{[1
]}

Ooms, KJ ^{[1
]}

Halchuk, PA ^{[1
]}

机构：

[1] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 06期

关键词：

D O I：

10.1039/b009133m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two newly identified structures arise upon the crystallisation of the p-tert-butylcalix[4]arene host molecule from tetradecane: the guest-free, self-included host structure, and a 1:1 host-guest structure in which the paraffin guest is anchored in the bowl-shaped host cavity and intercalates layers of host molecules in a lamellar structure reminiscent of clays.

引用

页码：565 / 566

页数：2

共 12 条

[1] CRYSTAL AND MOLECULAR-STRUCTURE OF CYCLO(QUATER[(5-TERT-BUTYL-2-HYDROXY-1,3-PHENYLENE)METHYLENE]) TOLUENE (1-1) CLATHRATE [J].

ANDREETTI, GD ;

UNGARO, R ;

POCHINI, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (22) :1005-1007

[2] ACTIVATION OF MONTMORILLONITE BY ION EXCHANGE AND SORPTION COMPLEXES OF TETRA-ALKYL AMMONIUM MONTMORILLONITES [J].

BARRER, RM ;

MACLEOD, DM .

TRANSACTIONS OF THE FARADAY SOCIETY, 1955, 51 (09) :1290-&

[3] Amine guest size and hydrogen-bonding influence the structures of p-tert-butylcalix[4]arene inclusions [J].

Brouwer, EB ;

Udachin, KA ;

Enright, GD ;

Ripmeester, JA .

CHEMICAL COMMUNICATIONS, 2000, (19) :1905-1906

[4] A chlorophobic pocket in the p-tert-butylcalix[4]arene cavity:: A test site for molecular recognition investigated by 13C CP MAS NMR and X-ray crystallography [J].

Brouwer, EB ;

Udachin, KA ;

Enright, GD ;

Ratcliffe, CI ;

Ripmeester, JA .

CHEMICAL COMMUNICATIONS, 1998, (05) :587-588

[5] t-Butylcalix[4]arene host-guest compounds: Structure and dynamics [J].

Brouwer, EB ;

Ripmeester, JA ;

Enright, GD .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1996, 24 (1-2) :1-17

[6]

BROUWER EB, 2001, DYNAMIC STRUCTURES H, P296

[7] NOVEL LAYER STRUCTURE OF SODIUM CALIX[4]ARENESULFONATE COMPLEXES - A CLASS OF ORGANIC CLAY MIMICS [J].

COLEMAN, AW ;

BOTT, SG ;

MORLEY, SD ;

MEANS, CM ;

ROBINSON, KD ;

ZHANG, HM ;

ATWOOD, JL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (10) :1361-1362

[8] SELF INCLUSION IN A CALIX[5]ARENE STRUCTURE - STRUCTURE OF THE CONE CONFORMER OF A PENTAHYDROXY-P-TERT-BUTYLCALIX[5]ARENE [J].

GALLAGHER, JF ;

FERGUSON, G ;

BOHMER, V ;

KRAFT, D .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 :73-77

[9]

Gutsche C.D., 1998, CALIXARENES REVISITE

[10] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473

← 1 2 →