8-hydroxyquinoline derivative as a fluorescent chemosensor for zinc ion

被引:11
作者
Kawakami, J [1 ]
Ohta, M [1 ]
Yamauchi, Y [1 ]
Ohzeki, K [1 ]
机构
[1] Hirosaki Univ, Dept Mat Sci & Technol, Fac Sci & Technol, Hirosaki, Aomori 0368561, Japan
关键词
D O I
10.2116/analsci.19.1353
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
8-Hydroxyquinoline derivative 1 as a fluorescent chemosensor for Zn2+ was synthesized. Because Cd2+ is often found with Zn2+ in the environment and can form fluorescent complexes with chelating fluorophores, a potentially important property of chemosensors for Zn2+ is their selectivity for Zn2+ over Cd2+. The Zn2+ or Cd2+ complexes of 1 gave an emission band from the 1: 1 complex, but the fluorescence intensity for Cd2+ was a half of that for Zn2+. Ligand 1 is suited for use as a fluorescent chemosensor for Zn2+.
引用
收藏
页码:1353 / 1354
页数:2
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