Characterization of foxing stains by chemical and spectrometric methods

被引:26
作者
Bicchieri, M
Pappalardo, G
Romano, FP
Sementilli, FM
De Acutis, R
机构
[1] Ist Cent Patol Libro, Chim Lab, I-00184 Rome, Italy
[2] LANDIS, Lab Nazl Sud, Ist Nazl Fis Nucl, I-95100 Catania, Italy
[3] Univ Catania, Dipartimento Fis, I-95100 Catania, Italy
关键词
D O I
10.1515/REST.2001.1
中图分类号
G25 [图书馆学、图书馆事业]; G35 [情报学、情报工作];
学科分类号
1205 ; 120501 ;
摘要
Foxing stains on six different papers from the 16(th)-18(th) centuries and additionally fox-like stains produced by dripping different amounts (1, 3 and 5 mul) of solutions of FeCl3, KCl and FeCl3+KCl (5.10(-3) M) on modern paper and artificially ageing were analyzed for chromaticity, fluorescence under W illumination, carbonyl content, thickness and submitted to IR spectroscopy and XRF spectrometry. As a result it is stated that the foxing phenomenon is related to a strong oxidation of the cellulose chain. Not regarding certain and possibly specific differences between different kinds of foxing stains, this strong oxidation is the only common characteristics for foxed areas.
引用
收藏
页码:1 / 19
页数:19
相关论文
共 22 条
[1]  
ANDREWS GC, 1980, TETRAHEDRON LETT, V21, P679
[2]  
ARAI H, 1988, INT I CONS CONS FAR, P11
[3]  
ARAI H, 1987, 8 TRIENN M SYDN, P1165
[4]  
BECKWITH T. D., 1940, Publ. Univ. Calif., biol Sci., V1, P299
[5]   A quantitative measure of borane tert-butylamine complex effectiveness in carbonyl reduction of aged papers [J].
Bicchieri, M ;
Bella, M ;
Semetilli, F .
RESTAURATOR-INTERNATIONAL JOURNAL FOR THE PRESERVATION OF LIBRARY AND ARCHIVAL MATERIAL, 1999, 20 (01) :22-29
[6]   The bleaching of paper by reduction with the borane tert-butylamine complex [J].
Bicchieri, M ;
Brusa, P .
RESTAURATOR-INTERNATIONAL JOURNAL FOR THE PRESERVATION OF LIBRARY AND ARCHIVAL MATERIAL, 1997, 18 (01) :1-11
[7]  
BICCHIERI M, 1999, 2 INT C SCI TECHN SA
[8]  
BICCHIERI M, 1999, INT C CONS REST ARCH, P695
[9]  
BIOCCHIERI M, 1999, CAB NEWSLETTER, V4, P7
[10]  
BURGESS HD, 1990, 9 TRIENN M ICOM COMM, V2, P447