Synthesis and structural characterisation of the novel metallasiloxane compound [Cp(2)(*) ZrOSiPh(2)OLiOH](2)

被引：6

作者：

Abrahams, I ^{[1
]}

Simon, C ^{[1
]}

Motevalli, M ^{[1
]}

Shah, SAA ^{[1
]}

Sullivan, AC ^{[1
]}

机构：

[1] UNIV LONDON QUEEN MARY & WESTFIELD COLL,DEPT CHEM,LONDON E1 4NS,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 521卷 / 1-2期

关键词：

silicon; zirconium; metallasiloxane; cyclopentadienyl; metallocene; crystal structure;

D O I：

10.1016/0022-328X(96)06360-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions between Cp(2)ZrCl(2) or Cp(2)*ZrCl2 with in situ generated Ph(2)Si(OLi)(2) gave unexpected dimeric cyclozirconasiloxane products incorporating LIOH within the chelate-bridging unit OSiPh(2)OLi(OH). The crystal structure of [Cp(2)*ZrOSiPh(2)OLiOH](2) is reported and the origin of the LiOH discussed.

引用

页码：301 / 304

页数：4

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