Strong lateral growth and crystallization via two-dimensional allotropic transformation of semi-metal Bi film

Two-dimensional (2D) nano-objects, such as metallic nanofilms are the most fundamental building blocks for nanoelectronics devices. However, the fabrication of highly ordered nanofilms has been difficult because of well known Stranski-Krastanov growth, which results in rough growth front and high density grains. Here we report on the unusual high-quality film growth of Bi on a Si surface with atomic-level surface/interface smoothness and high film crystallinity. The formation of a newly discovered 2D allotrope was clarified to initiate its strong 2D growth. Above several-monolayer thickness, the 2D allotrope transforms into a single-crystalline film with bulk-like layered structure. Our study unveils the atomistic growth process of nano-sized Bi, and the obtained knowledge here will be generally applicable for the fabrication of various nano-devices using this intriguing material that shows rich thermal, magnetic, electronic properties in nanometer scale. (c) 2005 Elsevier B.V. All rights reserved.