Synthesis and properties of new thiacalixarene derivatives with palladium ion

被引：11

作者：

Ye, ZF

Pan, ZG

He, WJ

Shi, XF

Zhu, LG ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2001年 / 40卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

electrospray mass spectrometry; palladium ion; thiacalix[4]arene;

D O I：

10.1023/A:1011140622020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three new thiacalix[4]arene derivatives, 5,11,17,23-tetra-tert-butyl-25,27-di(2-hydroxyethoxy)-26,28-dihydroxythiacalix-{}[4]arene (2), 5,11,17,23-tetra-tert-25, 26,27,28-tetrakis[(methylcarboxyl)methoxy]thiacalix[4]arene (3), 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis(2-hydroxy-1-propanoxy)thiacalix[4]arene (4), were synthesized for the first time. The coordination properties of thiacalix[4]arene(1) and its derivatives (2 and 4) were investigated by detecting the interactions between these compounds and two palladium complexes, cis-[Pd(en)(H2O)(2)](2+) and cis-[Pd(dtco-3-OH)(H2O)(2)](2+), by means of electrospray ionization mass spectrometry (ESI-MS) technique.

引用

页码：89 / 93

页数：5

共 19 条

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