The reactivity of 1,1-diamino-2,2-dinitroethene (FOX-7)

被引：135

作者：

Hervé, G ^{[1
]}

Jacob, G ^{[1
]}

Latypov, N ^{[1
]}

机构：

[1] Swedish Def Res Agcy, FOI, S-14725 Tumba, Sweden

来源：

TETRAHEDRON | 2005年 / 61卷 / 28期

关键词：

nitro compounds; electrophilic reactions; ethelenic compounds; nitration;

D O I：

10.1016/j.tet.2005.05.010

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

The reactivity of 1,1-diamino-2,2-dinitroethene (DADNE) or FOX-7 was studied. Various reactions like cycloadditions, nitration, halogenation and acylation were performed in order to evaluate the reactivity of the C-C double bond and the amino moieties. Several products were isolated and two of them were characterised by X-ray analysis. Two reactive sites were identified. The chemical behaviour of DADNE is also discussed. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：6743 / 6748

页数：6

共 19 条

[1]

[Anonymous], 1971, NITRILE OXIDES

[2]

NITRATION OF 1,1-DIAMINO-2,2-DINITROETHYLENES [J].