Influence of aluminium oxide on intensities of Sm3+ and Pr3+ spectral transitions in sol-gel glasses

被引:39
作者
Patra, A
Reisfeld, R [1 ]
Minti, H
机构
[1] Hebrew Univ Jerusalem, Dept Inorgan & Analyt Chem, IL-91940 Jerusalem, Israel
[2] Cent Glass & Ceram Res Inst, Sol Gel Div, Calcutta 700032, W Bengal, India
关键词
sol-gel; silica-alumina glasses; fluorescence; rare earth ions; absorption;
D O I
10.1016/S0167-577X(98)00114-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The transition probabilities of Pr, Sm and Nd ions in sol-gel glasses are increased by addition of Al3+ as a result of lowering of the site symmetry in which the ion is situated. The addition of Al has even a greater effect on luminescent efficiencies than on absorption strengths. The effect is a result of a decrease of aggregation of the ions in presence of Al circumventing the cross-relaxation process. (C) 1998 Elsevier Science B.V, All rights reserved.
引用
收藏
页码:325 / 329
页数:5
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