Phase relations in the V2O5-MoO3-α-Sb2O4 system in the solid state in air atmosphere

被引：7

作者：

Filipek, E ^{[1
]}

机构：

[1] Tech Univ Szczecin, Inst Chem & Environm Protect, PL-71065 Szczecin, Poland

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2001年 / 64卷 / 03期

关键词：

DTA; phase equilibrium; Sb3V2Mo3O21; compound; XRD;

D O I：

10.1023/A:1011520323773

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The phase equilibria established in the V2O5-MoO3-alpha -Sb2O4 system in the solid state in an air atmosphere were examined by using XRD and DTA methods. The obtained results allowed us to find that in this system a novel compound is formed involving three oxides. Its formula can be written as Sb3V2Mo3O21. The synthesis of this compound requires picking up the atmospheric oxygen. X-ray characteristics of this compound were determined and it was found that it melted incongruently at 740 degreesC. The results obtained until now allow us to divide the investigated V2O5-MoO3-alpha -Sb2O4 system into five partial subsystems.

引用

页码：1095 / 1103

页数：9

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