Synthesis and characterization of ruthenium-osmium complexes containing μ-bisalkenyl, μ-alkenylvinylidene, and μ-alkenylcarbene bridge ligands

被引：46

作者：

Buil, ML ^{[1
]}

Esteruelas, MA ^{[1
]}

机构：

[1] Univ Zaragoza, Dept Quim Inorgan, Inst Ciencia Mat Aragon, CSIC, E-50009 Zaragoza, Spain

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 09期

关键词：

D O I：

10.1021/om9810192

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The metaloalkyne complex Ru{(E)-CH=CH-(CH2)(4)-C equivalent to CH}Cl(CO)((PPr3)-Pr-i)(2) reacts with OsHCl(CO)-((PPr3)-Pr-i)(2) to give the heterodinuclear-mu-bisalkenyl derivative ((PPr3)-Pr-i)(2)(CO)ClRu{(E)-CH=CH-(CH2)(4)-CH=CH-(E)}OsCl(CO)((PPr3)-Pr-i)(2) via the hydrido-vinylidene intermediate ((PPr3)-Pr-i)(2)(CO)ClRu{(E)-CH=CH-(CH2)(4)- CH=C}-OsHCl(CO)((PPr3)-Pr-i)(2). The reaction of the heterodinuclear-mu-bisalkenyl complex with HCl selectively affords ((PPr3)-Pr-i)(2)(CO) ClRu{(E)-CH=CH-(CH2)(5)-CH}OsCl2(CO)-((PPr3)-Pr-i)(2).

引用

页码：1798 / 1800

页数：3

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