Decomposition kinetics, arrhenius parameters, and bond dissociation energies for alkoxyamines of relevance in "living" free radical polymerization

被引：107

作者：

Skene, WG

Belt, ST

Connolly, TJ

Hahn, P

Scaiano, JC ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

[2] Univ Plymouth, Dept Environm Sci, Plymouth PL4 8AA, Devon, England

来源：

MACROMOLECULES | 1998年 / 31卷 / 25期

关键词：

D O I：

10.1021/ma9812229

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

[No abstract available]

引用

页码：9103 / 9105

页数：3

共 30 条

[1] Influence of acids on reaction rates of free radical scavenging by TEMPO. Relevance to ''living'' free radical polymerizations [J].

Baldovi, MV ;

Mohtat, N ;

Scaiano, JC .

MACROMOLECULES, 1996, 29 (16) :5497-5499

[2] HEATS OF FORMATION OF C1-C4 ALKYL NITRITES (RONO) AND THEIR RO-NO BOND-DISSOCIATION ENERGIES [J].

BATT, L ;

CHRISTIE, K ;

MILNE, RT ;

SUMMERS, AJ .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1974, 6 (06) :877-885

[3] KINETIC DATA FOR COUPLING OF PRIMARY ALKYL RADICALS WITH A STABLE NITROXIDE [J].

BECKWITH, ALJ ;

BOWRY, VW ;

OLEARY, M ;

MOAD, G ;

RIZZARDO, E ;

SOLOMON, DH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (13) :1003-1004

[4] KINETICS OF NITROXIDE RADICAL TRAPPING .1. SOLVENT EFFECTS [J].

BECKWITH, ALJ ;

BOWRY, VW ;

INGOLD, KU .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) :4983-4992

[5] KINETICS OF NITROXIDE RADICAL TRAPPING .2. STRUCTURAL EFFECTS [J].

BOWRY, VW ;

INGOLD, KU .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) :4992-4996

[6] ABSOLUTE RATE CONSTANTS FOR THE REACTIONS OF SOME CARBON-CENTERED RADICALS WITH 2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL [J].

CHATEAUNEUF, J ;

LUSZTYK, J ;

INGOLD, KU .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (08) :1629-1632

[7] Photochemical synthesis of TEMPO-capped initiators for ''living'' free radical polymerization [J].

Connolly, TJ ;

Baldovi, MV ;

Mohtat, N ;

Scaiano, JC .

TETRAHEDRON LETTERS, 1996, 37 (28) :4919-4922

[8] Thermolysis of a tertiary alkoxyamine. Recombination and disproportionation of alpha-phenethyl/diethyl nitroxyl radical pairs [J].

Engel, PS ;

Duan, SM ;

Arhancet, GB .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (11) :3537-3541

[9] The persistent radical effect in ''living'' radical polymerization [J].

Fischer, H .

MACROMOLECULES, 1997, 30 (19) :5666-5672

[10]

FISCHER H, 1986, J AM CHEM SOC, V108, P3925, DOI 10.1021/ja00274a012

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