Synthesis and crystal structure of a novel zinc(II) complex [Zn(pbp)(2)](ClO4)(2)

被引：9

作者：

Liu, CM

Xiong, RG

Zuo, JL

You, XZ

机构：

[1] NANJING UNIV, CTR ADV STUDIES SCI & TECHNOL MICROSTRUCT, INST COORDINAT CHEM, NANJING 210093, PEOPLES R CHINA

[2] ACAD SINICA, FUJIAN INST RES STRUCT MATTER, FUZHOU LAB STRUCT CHEM, FUZHOU 350002, PEOPLES R CHINA

来源：

POLYHEDRON | 1996年 / 15卷 / 12期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/0277-5387(95)00446-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Zn(pbp)(2)](ClO4)(2) [pbp = N-(1-(2-pyrid-2-yl)benzoylidene)1,3-propanediamine] was obtained by reaction of 2-benzoylpyridine and 1,3-propane diamine with zinc perchlorate in ethanol. A single crystal X-ray study shows that the complex is monomeric with the zinc atom coordinated by six nitrogen atoms from two singly neutral tridentate ligands to form a distorted octahedral geometry. The Zn-N bond lengths range from 2.070(5) to 2.123(6) Angstrom.

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页码：2051 / 2055

页数：5

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