Polymer-based adsorption medium prepared using a fragment imprinting technique for homologues of chlorinated bisphenol A produced in the environment

被引:42
作者
Kubo, T
Hosoya, K [1 ]
Watabe, Y
Ikegami, T
Tanaka, N
Sano, T
Kaya, K
机构
[1] Kyoto Inst Technol, Dept Polymer Sci, Sakyo Ku, Kyoto 6068585, Japan
[2] Natl Inst Environm Studies, Lab Intellectual Fundamentals Environm Studies, Tsukuba, Ibaraki 3058506, Japan
关键词
fragment imprinting; molecular recognition; polymer-based adsorbents; endocrine-disrupting chemicals; bisphenol A;
D O I
10.1016/j.chroma.2003.12.050
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
A polymer-based adsorption medium having molecular recognition ability for homologues of chlorinated bisphenol A produced in environment was prepared using a fragment imprinting technique. 2,6-Dimethyl phenol was utilized as a pseudo-template molecule and the adsorption media prepared was evaluated by high performance liquid chromatography (HPLC) and solid-phase extraction (SPE). As results, the adsorption medium showed preferable chromatographic retention and specific adsorption ability for the chlorinated bisphenol As having chlorine substituents at 3,5-positions through fragment imprinting effect. (C) 2004 Elsevier B.V. All fights reserved.
引用
收藏
页码:37 / 41
页数:5
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