Amination and amidation of aryl iodides catalyzed by copper(I)-phenanthroline complexes

被引：52

作者：

Moriwaki, K ^{[1
]}

Satoh, K ^{[1
]}

Takada, M ^{[1
]}

Ishino, Y ^{[1
]}

Ohno, T ^{[1
]}

机构：

[1] Osaka Municipal Tech Res Inst, Joto Ku, Osaka 5368553, Japan

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 44期

关键词：

amination; amidation; N-arylation; phenanthroline; copper; complex; catalysis;

D O I：

10.1016/j.tetlet.2005.08.146

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Four kinds of copper(I)-pherianthroline complexes ([Cu-I(phen)(2)]Cl, [Cu-I(phen)Cl](2), [Cu-I(phen)(2)]BF4, and Cu-I(phen)PPh3Cl) were prepared and used as catalysts for amination and amidation of aryl iodide to investigate the influence on the yields of products due to differences of the structures, These complexes were found to work as catalysts on these reactions and showed that the differences of structures of copper(l) complexes significantly influenced the yield of aryl-nitrogen bond forming processes. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：7559 / 7562

页数：4

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