Examining the thermolysis reactions of nanoscopic Mn12 single molecule magnets

被引：15

作者：

Gerbier, P

Ruiz-Molina, D

Gómez, J

Wurst, K

Veciana, J

机构：

[1] CSIC, Inst Ciencia Mat Barcelona, Cerdanyola Del Valles 08193, Spain

[2] Univ Montpellier 2, UMR 5637, F-34095 Montpellier, France

[3] Univ Innsbruck, A-6020 Innsbruck, Austria

来源：

POLYHEDRON | 2003年 / 22卷 / 14-17期

关键词：

Mn-12; single molecule magnets; thermal stability; thermolytic synthetic methods;

D O I：

10.1016/S0277-5387(03)00158-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermal behavior of three Mn-12 single molecule magnets [Mn12O12(O2CC6H5)(16)(H2O)(4)].CH2Cl2 C6H5CO2H (1), [Mn12O12(O2C'Bu)(16)(H2O)(4)] (2) and [Mn12O12(O2CCHCl2)(16)(H2O)(4)] (3) is reported. Aromatic ligands allow the complex 1 to be stable up to 300 degreesC whereas alkyl groups decrease drastically the domain of thermal stability for the complexes 2 and 3. Moreover, the thermal decarboxylation of complexes 2 and 3 generates [Mn6O2(O2CR)(10)L-4] (L = H2O, HO2CR) complexes as characterized by single crystal X-ray diffraction when R = 'Bu. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：1951 / 1955

页数：5

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