Origin of Piezoelectricity in an Electrospun Poly(vinylidene fluoride-trifluoroethylene) Nanofiber Web-Based Nanogenerator and Nano-Pressure Sensor

被引:309
作者
Mandal, Dipankar [1 ]
Yoon, Sun [1 ]
Kim, Kap Jin [1 ]
机构
[1] Kyung Hee Univ, Coll Engn, Dept Adv Mat Engn Informat & Elect, Yongin 446701, Gyeonggi Do, South Korea
关键词
curie transition temperature; electrospun nanofiber web; infrared spectroscopy; nanogenerator; preferential dipole orientation; P(VDF-TrFE); FERROELECTRIC POLYMERS;
D O I
10.1002/marc.201100040
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A single stage electrospinning process can give rise to preferentially oriented induced dipoles in poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] nanofibers. The piezoelectricity of as-electrospun P(VDF-TrFE) nanofiber webs opens up new possibilities for their use as a flexible nanogenerators and nano-pressure sensors. In this work, the origin of the piezoelectricity has been spotlighted by randomization of the induced dipoles at the Curie temperature and analyzed by polarized FT-IR spectroscopic techniques as well as by detecting the piezoelectric signal from a nano-pressure sensor.
引用
收藏
页码:831 / 837
页数:7
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