A simple, CIP-based notation system for the unambiguous specification of asymmetric reactions

被引：3

作者：

Avalos, M ^{[1
]}

Babiano, R ^{[1
]}

Cintas, P ^{[1
]}

Jimenez, JL ^{[1
]}

Palacios, JC ^{[1
]}

机构：

[1] UNIV EXTREMADURA,FAC CIENCIAS,DEPT QUIM ORGAN,E-06071 BADAJOZ,SPAIN

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 08期

关键词：

D O I：

10.1016/0957-4166(96)00288-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A set of stereochemical rules based on the CIP configurational descriptors have been proposed for the specification of the stereochemical outcome of asymmetric transformations. This simple and unambiguous system denotes the steric approach involving prochiral faces and stereogenic centers of reactants, either in enantio- or diastereoselective synthesis. The descriptors form chiral codes of symbols and numbers, which are susceptible of computerization. A brief discussion and comparison with other terms currently employed in dynamic stereochemistry are also given. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：2333 / 2342

页数：10

共 56 条

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