Green organophotocatalysis. TiO2-induced enantioselective α-oxyamination of aldehydes

被引：36

作者：

Ho, Xuan-Huong ^{[1
]}

Kang, Min-Jung ^{[1
]}

Kim, Seung-Joo ^{[1
]}

Park, Eun Duck ^{[1
]}

Jang, Hye-Young ^{[1
]}

机构：

[1] Ajou Univ, Div Energy Syst Res, Suwon 443749, South Korea

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2011年 / 1卷 / 06期

关键词：

AROMATIC ALCOHOLS; AEROBIC OXIDATION; SOMO CATALYSIS; TIO2; LIGHT; ORGANOCATALYSIS; PHOTOCATALYSIS; HYDROGENATION; ALKYLATION; ARYLATION;

D O I：

10.1039/c1cy00183c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Asymmetric C-O bond formation with various aldehydes is examined under conditions of environmentally benign photo-organocatalysis. A heterogeneous TiO2 photocatalyst is used as a photooxidant in place of toxic and expensive chemical oxidants, for the first time in chemo- and stereoselective bond formation.

引用

页码：923 / 926

页数：4

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