Efficient and practical aerobic radical addition of thiophosphites to alkenes

被引：35

作者：

Gautier, A

Garipova, G

Dubert, O

Oulyadi, H

Piettre, SR ^{[1
]}

机构：

[1] Univ Rouen, IRCOF, Lab Fonct Azotees & Oxygenees Complexes, CNRS,UMR 6014, F-76821 Mont St Aignan, France

[2] Kazan VI Lenin State Univ, Dept Chem, Lab Elementoorgan & Supramol Cpds, Kazan 420008, Russia

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 33期

关键词：

boron; phosphonothioate; thiophosphite; radical additions; cascade radical cyclization;

D O I：

10.1016/S0040-4039(01)01074-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thiophosphites, but not phosphites, add onto alkenes under very mild conditions when treated with triethylborane and oxygen, and deliver the expected adducts in high isolated yields. This method, featuring a high atom economy, complements those described in literature and can be used to initiate tandem cascade processes. (C) 2001 Published by Elsevier Science Ltd.

引用

页码：5673 / 5676

页数：4

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