Homochiral porous metal-organic frameworks: Why and how?

被引:226
作者
Lin, WB [1 ]
机构
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
关键词
crystal engineering; asymmetric catalysis;
D O I
10.1016/j.jssc.2005.06.013
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This paper highlights the most significant recent advances in the synthesis, characterization, and applications of single-crystalline homochiral porous metal-organic frameworks (MOFs). The motivations for the synthesis of homochiral porous solids and the strategies on how they can be designed are provided. The latest examples of chiral separation and Lewis acid heterogeneous asymmetric catalysis using homochiral porous MOFs are presented. (c) 2005 Elsevier Inc. All rights reserved.
引用
收藏
页码:2486 / 2490
页数:5
相关论文
共 36 条
  • [1] STRUCTURE OF THE MICROPOROUS TITANOSILICATE ETS-10
    ANDERSON, MW
    TERASAKI, O
    OHSUNA, T
    PHILIPPOU, A
    MACKAY, SP
    FERREIRA, A
    ROCHA, J
    LIDIN, S
    [J]. NATURE, 1994, 367 (6461) : 347 - 351
  • [2] Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
  • [3] 2-Z
  • [4] Permanent microporosity and enantioselective sorption in a chiral open framework
    Bradshaw, D
    Prior, TJ
    Cussen, EJ
    Claridge, JB
    Rosseinsky, MJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) : 6106 - 6114
  • [5] From microporous to mesoporous molecular sieve materials and their use in catalysis
    Corma, A
    [J]. CHEMICAL REVIEWS, 1997, 97 (06) : 2373 - 2419
  • [6] Interlocked chiral nanotubes assembled from quintuple helices
    Cui, Y
    Lee, SJ
    Lin, WB
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (20) : 6014 - 6015
  • [7] Cui Y, 2002, ANGEW CHEM INT EDIT, V41, P1159, DOI 10.1002/1521-3773(20020402)41:7<1159::AID-ANIE1159>3.0.CO
  • [8] 2-5
  • [9] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage
    Eddaoudi, M
    Kim, J
    Rosi, N
    Vodak, D
    Wachter, J
    O'Keeffe, M
    Yaghi, OM
    [J]. SCIENCE, 2002, 295 (5554) : 469 - 472
  • [10] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks
    Eddaoudi, M
    Moler, DB
    Li, HL
    Chen, BL
    Reineke, TM
    O'Keeffe, M
    Yaghi, OM
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) : 319 - 330