Kinetic modelling of esterification reactions catalysed by immobilized lipases

被引：32

作者：

Garcia, T

Coteron, A

Martinez, M

Aracil, J

机构：

[1] Department of Chemical Engineering, Faculty of Chemistry, Complutense University

来源：

CHEMICAL ENGINEERING SCIENCE | 1996年 / 51卷 / 11期

关键词：

D O I：

10.1016/0009-2509(96)00162-5

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The kinetics of the synthesis of several esters of different chain length and physical properties was studied. A commercial Candida antarctica lipase was used as catalyst for the synthesis of oleyl oleate, isopropyl oleate, isopropyl palmitate, myristyl myristate, cetyl oleate, and oleyl 2-methylbutyrate. A general kinetic model was derived and tested experimentally for the synthesis of the above esters. The general kinetic model took a different shape for each particular esterification reaction, depending on the significance of the different terms. The corresponding parameters were calculated by non-linear regression. The kinetic models were found to describe the experimental values adequately.

引用

页码：2841 / 2846

页数：6

共 6 条

[1] ENZYMATIC-SYNTHESIS OF ESTERS USING AN IMMOBILIZED LIPASE [J].