Growth and properties of the organometallic nonlinear optical crystal: Semicarbazide cadmium chloride (SCCC)

被引：7

作者：

Wang, BG

机构：

[1] Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai

[2] R and D Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Jiading

来源：

CRYSTAL RESEARCH AND TECHNOLOGY | 1996年 / 31卷 / 04期

关键词：

D O I：

10.1002/crat.2170310404

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Semicarbazide cadmium chloride (SCCC) is an organometallic nonlinear optical crystal. Preparation and crystal growth of SCCC have been studied, thermal and IR spectral properties of the crystal are characterized. Investigations of the molecular and crystal structures show that there is a large charge-transfer bridge in the molecule, and that the crystal has a distorted polyhedrally-coordinated structure. The relations between the structures and NLO effects of complex crystals have been discussed, and optimization of structures of organometallic NLO crystals are suggested.

引用

页码：421 / 428

页数：8

共 10 条

[1]

CHEN C, 1977, SCI CHINA, V6, P579

[2] THE DEVELOPMENT OF NEW NLO CRYSTALS IN THE BORATE SERIES [J].