The electro-oxidation of dimethylamine borane: Part 2, in situ FTIR on single-crystal gold electrodes

被引：9

作者：

Plana, Daniela ^{[1
]}

Rodriguez, Paramaconi ^{[2
]}

Koper, Marc T. M. ^{[2
]}

Dryfe, Robert A. W. ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[2] Leiden Univ, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands

来源：

ELECTROCHIMICA ACTA | 2011年 / 56卷 / 22期

基金：

英国工程与自然科学研究理事会;

关键词：

DMAB oxidation; FTIR; Single-crystal gold electrodes; Reducing agent; Electroless deposition; BOROHYDRIDE OXIDATION REACTION; REDUCING AGENTS; ALKALINE-SOLUTIONS; INFRARED-SPECTRA; AMMONIA-BORANE; AQUEOUS-MEDIA; FUEL-CELLS; DEPOSITION; MECHANISM; SURFACE;

D O I：

10.1016/j.electacta.2011.06.072

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Dimethylamine borane (DMAB) electro-oxidation in alkaline media was studied using static and rotating gold single-crystal electrodes in the hanging-meniscus configuration. DMAB oxidation showed a strong sensitivity towards surface structure on gold electrodes. In situ Fourier transform infrared (FTIR) spectroscopy revealed that the potential-dependent cleavage of the B-N bond is one of the initial steps of the oxidation process. FTIR also showed that dimethylamine is oxidised in the potential range of gold oxide formation. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：7637 / 7643

页数：7

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