Solar steam reforming of natural gas for hydrogen production using molten salt heat carriers

被引:72
作者
Giaconia, Alberto [1 ]
de Falco, Marcello [2 ]
Caputo, Giampaolo [1 ]
Grena, Roberto [1 ]
Tarquini, Pietro [1 ]
机构
[1] ENEA Res Ctr Casaccia, I-00123 Rome, Italy
[2] Univ Roma La Sapienza, Dept Chem Engn, I-00184 Rome, Italy
关键词
energy; green engineering; process simulation; membrane separations; hydrocarbon processing;
D O I
10.1002/aic.11510
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The utilization of concentrated solar energy as external heat source for methane steam reforming has been investigated. Molten salts at temperatures up to 550 degrees C can be used as solar heat carrier and storage system, and hydrogen selective membranes can be used to drive reforming reaction at lower temperatures than conventional (<550 degrees C), with hydrogen purification achieved thereby. The combination of new technologies such as membranes and membrane reactors, concentrating solar power (CSP) systems, and molten salt heat carriers, allows a partial decarbonation of the fossil fuel together with the possibility to carry solar energy in the current natural gas grid. Different plant configurations and operating conditions have been analyzed using a mathematical model and AspenPlus simulator. (C) 2008 American Institute of Chemical Engineers.
引用
收藏
页码:1932 / 1944
页数:13
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