Synthesis and structure of novel bridged dinuclear indium complexes

被引:39
作者
Zhou, YL [1 ]
Richeson, DS [1 ]
机构
[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA
关键词
D O I
10.1021/ic951241o
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The unique, lantern-type structure of 1 has two In centers in unusual square-based pyramidal environments consisting of the four formamidinate N atoms with a terminal chloride occupying the apical position. Two routes for the formation of 1 and a stepwise pathway for the preparation of the dimethyl analogue are presented. Without the possibility of In-In interactions it would appear that steric features are the primary cause for the formation of these compounds.
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页码:1423 / &
页数:3
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