Electrospray mass spectrometry of [Ru4(η6-C6H6)4(OH)4]4+:: first direct evidence for the persistence of the cubane unit in solution and its role as a precatalyst in the hydrogenation of benzene

被引：24

作者：

Dyson, PJ ^{[1
]}

Russell, K

Welton, T

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 10期

基金：

英国工程与自然科学研究理事会;

关键词：

ruthenium; cubane; electrospray mass spectrometry; benzene hydrogenation; catalysis;

D O I：

10.1016/S1387-7003(01)00269-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electrospray ionisation mass spectrum of [Ru-4(eta (6)-C6H6)(4)(OH)(4)](4+) shows that the main species present in aqueous solution are based on the intact cubane tetramer and the dimer [Ru-2(eta (6)-C6H6)(2)(OH)(2)](2+). The latter species is an active benzene hydrogenation catalyst. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：571 / 573

页数：3

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